Shear-induced smectic order in isotactic polypropylene reviseted

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DOI http://dx.doi.org/10.1021/ma062375w
Reference D. Byelov, P. Panine and W.H. de Jeu, Shear-induced smectic order in isotactic polypropylene reviseted, Macromolecules 40, 288-289 (2007)

We provide evidence that earlier reported smectic ordering in the melt of isotactic polypropylene is not intrinsic to the system but results from the presence of small quantities of calcium stearate. No causal relation exists between this effect and the crystallization properties of iPP.