Dissociation of polyatomic ions at surfaces: the influence of mechanical and electronic energy transfer

The dissociative scattering of CF₃⁺ions from a clean Ag(111) surface was explored in the energy range 100-600 eV. Both negative (CF₃^–, CF₂^–, and F^–) and positive ions (CF⁺ and C⁺) were formed. The complete dissociation of the CF₃⁺ molecular ions into C⁺ fragments was found to be feasible at low (normal) incoming energies. We conclude that the breaking of three C-F bonds is due to concerted electronic and mechanical energy transfer. The azimuthal orientation of the crystal has a large influence on the degree of dissociation, which indicates the importance of direct momentum transfer.