Cubatic phase for tetrapods

Back to all publications

Publication date
DOI http://dx.doi.org/10.1063/1.1649733
Reference R. Blaak, B.M. Mulder and D. Frenkel, Cubatic phase for tetrapods, J. Chem. Phys. 120, 5486-5492 (2004)
Group Theory of Biomolecular Matter

We investigate the phase behavior of tetrapods, hard nonconvex bodies formed by four rods connected under tetrahedral angles. We predict that, depending on the relative lengths of the rods these particles can form a uniaxial nematic phase, and more surprisingly they can exhibit a cubatic phase, a special case of the biaxial nematic phase. These predictions may be experimentally testable, as experimental realizations of tetrapods have recently become available.