Phase behavior of lyotropic liquid crystals

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Reference D. Frenkel: Phase behavior of lyotropic liquid crystals In: Advances in the Computer Simulations of Liquid Crystals; Conf. Erice, June 1998 /ed. P. Pasini and C. Zannoni, Kluwer, 2000. - pp. 51-72

In these lectures, I discuss techniques to compute the phase diagram of lyotropic liquid crystals. I review the standard techniques to compute the free-energy of various phases. Subsequently, I focus on phase transitions in liquid crystals. Recent techniques to determine the dependence of phase boundaries on the shape and flexibility of the constituent molecules, are discussed. Finally, I devote attention to Monte Carlo techniques that are particularly suited to study the phase behavior of flexible molecules.